When you’re on a call, the screen shows call options.

Tap Mute. You can still hear the caller, but the caller can’t hear you.
Tap Keypad.
Tap Speaker. The Button is labeled Audio Source when a Bluetooth device is available, which lets you select the Bluetooth device, iPhone, or Speaker Phone.
Tap Contacts.
Tap Hold. Neither party can hear the other.
Tap Add Call.
Press the Home
button, then tap an application icon.
Tap End Call. Or press the center button on your iPhone headset (or the equivalent button on your Bluetooth headset).